Synthesis, structure and properties of 1,19-disubstituted tetradehydrocorrin cobalt complexes.
Synthesis, structure and properties of 1,19-disubstituted tetradehydrocorrin cobalt complexes.
复制标题
1,19-二取代四氢咕啉钴配合物的合成、结构和性质。
DOI：
10.1016/s0162-0134(00)00178-1
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发表时间：
2001
影响因子：
3.9
通讯作者：
D. Dolphin
中科院分区：
文献类型：
--
作者：
C. Liu;A. Thompson;D. Dolphin
1,19-二取代四氢科林斯的环状结构与维生素B12中的科林斯环密切相关。我们在此报道了Co(I)-TDHC的分离和完整表征，x射线晶体结构和相关的Co（II）和Co（III）蛋白作为维生素b12配合物模型的完整表征。
1,19-Disubstituted tetradehydrocorrins have a ring structure that is closely related to the corrin ring found in vitamin B12. We herein report the isolation and full characterization of a Co(I)-TDHC species and X-ray crystal structures and full characterization of related Co(II) and Co(III) corrins as models for vitamin B12complexes.