Ni-Catalyzed Reduction of Inert C-O Bonds: A New Strategy for Using Aryl Ethers as Easily Removable Directing Groups
Ni-Catalyzed Reduction of Inert C-O Bonds: A New Strategy for Using Aryl Ethers as Easily Removable Directing Groups
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DOI：
10.1021/ja106943q
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发表时间：
2010-12-15
影响因子：
15
通讯作者：
Martin, Ruben
中科院分区：
文献类型：
--
作者：
Alvarez-Bercedo, Paula;Martin, Ruben
发展了一种有效的镍催化的惰性C-O键的还原裂解方法。该方法的特点是简单和范围广，从而允许在有机合成中使用芳基醚作为易于移除的导向基团。
An efficient Ni-catalyzed protocol for the reductive cleavage of inert C-O bonds has been developed. The method is characterized by its simplicity and wide scope, thereby allowing the use of aryl ethers as easily removable directing groups in organic synthesis.