Electronic structure of metal complexes containing π-cyclopentadienyl and related ligands. Part 1.—He(I) photoelectron spectra of some closed-shell metallocenes
Electronic structure of metal complexes containing π-cyclopentadienyl and related ligands. Part 1.—He(I) photoelectron spectra of some closed-shell metallocenes
复制标题
含有 π-环戊二烯基和相关配体的金属配合物的电子结构第 1 部分：一些闭壳茂金属的 He(I) 光电子能谱。
DOI：
10.1039/f29726801847
复制
发表时间：
1972
期刊：
影响因子：
--
通讯作者：
C. F. Pygall
中科院分区：
文献类型：
--
作者：
S. Evans;Malcolm L. H. Green;B. Jewitt;A. F. Orchard;C. F. Pygall
本文报道了茂金属化合物(C5H5)2V、(C5H5)2Cr、(C5H5)2Mn、(C5H5)2Co和(C5H5)2Ni及其1，1‘-二甲基衍生物的光电子能谱。用配位场理论讨论了金属的三维电离结构。(C5H4Me)2Mn的反常光谱被解释为气相中的高自旋/低自旋平衡。
He I photoelectron spectra are reported for the metallocene species (C5H5)2V, (C5H5)2Cr, (C5H5)2Mn, (C5H5)2Co and (C5H5)2Ni, and for their 1,1′-dimethyl derivatives. The metal 3d ionisation structure is discussed in terms of ligand field theory. The unusual spectrum of (C5H4Me)2 Mn is interpreted in terms of a high-spin/low-spin equilibrium in the gas phase.