Epitaxial Growth of Conductive Charge-transfer Complex in the Organized Molecular Film on Fluorinated Copolymer as Template
Epitaxial Growth of Conductive Charge-transfer Complex in the Organized Molecular Film on Fluorinated Copolymer as Template
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DOI：
10.14723/tmrsj.36.169
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发表时间：
2011-06
期刊：
影响因子：
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通讯作者：
Ryosuke Itagaki;J. Kusaka;M. Kubota;K. Kurosaka;Yoko Tatewaki;A. Fujimori
中科院分区：
文献类型：
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作者：
Ryosuke Itagaki;J. Kusaka;M. Kubota;K. Kurosaka;Yoko Tatewaki;A. Fujimori
通过面内 X 射线衍射 (XRD) 估算，烷基铵-Au 双(1, 3-二硫醇-2-硫酮-4, 5-二硫醇) ((dmit)2) 电荷转移复合物的有序分子膜在氟化共聚物上外延生长作为模板。在单晶中，双十二烷基铵-Au(dmit)2 分子堆积在三斜晶格中。从氢化固体多层膜的面内 XRD 测量来看，该配合物的烷基链也形成三斜晶系。该复合膜的斜方堆积形成于氟化结晶聚合物作为基底上。这种结构转变是由氟化共聚物的晶体结构作为模板引起的。另一方面，在非晶态含氟共聚物上形成的这些二维膜中的分子排列无序。
Epitaxial growth of organized molecular films of alkylammonium-Au bis(1, 3-dithiole-2-thione-4, 5-dithiolate) ((dmit)2) charge-transfer complex on fluorinated copolymer as template estimated by in-plane X-ray diffraction (XRD). In the single crystal, didodecylammonium-Au(dmit)2 molecules packed triclinic lattice. From the in-plane XRD measurement of multilayers on hydrogenated solids, alkyl-chains of this complex also formed triclinic system. The orthorhombic packing of this complex film formed on fluorinated crystalline polymer as substrate. This structural transition is induced by crystal structure of fluorinated copolymer as template. On the other hand, disordered molecular arrangement in these two-dimensional films formed on the amorphous fluorinated copolymer.