The characteristics of bio-oil produced from the pyrolysis of three marine macroalgae

The characteristics of bio-oil produced from the pyrolysis of three marine macroalgae
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DOI:
10.1016/j.biortech.2010.11.023
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发表时间:
2011-02-01
影响因子:
11.4
通讯作者:
Park, Young-Kwon
Park, Young-Kwon
中科院分区:
工程技术1区
文献类型:
--
作者:
Bae, Yoon Ju;Ryu, Changkook;Park, Young-Kwon

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研究了两种棕色大型藻类(裙带菜和海带)和一种红色大型藻类(紫菜)在 300-600 摄氏度的温度范围内热解生产生物油。大型藻类与木质纤维素土地生物质的不同之处在于其组成化合物以及高氮、硫和灰分含量。生物油的最大产量在500摄氏度下实现,产率在37.5wt.%和47.4wt.%之间。生物油中的主要化合物因大型藻类而异,并且与陆地生物质的生物油有很大不同,特别是在存在许多含氮化合物的情况下。气态产物。 CO2占主导地位,而C-1-C-4碳氢化合物在400℃及以上逐渐增加。通过酸洗对大型藻类进行预处理,有效降低了灰分含量。大型藻类的热解为原料生产提供了新的机会;然而,生物油作为燃料产品的利用需要进一步评估。 (C) 2010 Elsevier Ltd. 保留所有权利。
The pyrolysis of two brown macroalgae (Undaria pinnatifida and Laminaria japonica) and one red macroalgae (Porphyra tenera) was investigated for the production of bio-oil within the temperature range of 300-600 degrees C. Macroalgae differ from lignocellulosic land biomass in their constitutional compounds and high N, S and ash contents. The maximum production of bio-oil was achieved at 500 degrees C. with yields between 37.5 and 47.4 wt.%. The main compounds in bio-oils vary between macroalgae and are greatly different from those of land biomass, especially in the presence of many nitrogen-containing compounds. Of the gaseous products. CO2 was dominant, while C-1-C-4 hydrocarbons gradually increasing at 400 degrees C and above. The pretreatment of macroalgae by acid washing effectively reduced the ash content. The pyrolysis of macroalgae offers a new opportunity for feedstock production; however, the utilization of bio-oil as a fuel product needs further assessment. (C) 2010 Elsevier Ltd. All rights reserved.