Helical tetrathiafulvalene oligomers. Synthesis and properties of Bi-, ter-, and quatertetrathiafulvalenes
Helical tetrathiafulvalene oligomers. Synthesis and properties of Bi-, ter-, and quatertetrathiafulvalenes
复制标题
螺旋四硫富瓦烯低聚物。
作者：
Iyoda;Hara;Kuwatani;Nagase
一系列的完全甲基硫醇化的双，三，和quatertetrathiafulvalenes已被合成使用交叉和homocoupling反应的四硫富瓦烯锌衍生物;从螺旋四硫富瓦烯四聚体衍生的四价阳离子tetraradical表现出分子内协会的终端阳离子自由基。
A series of fully methylthiolated bi-, ter-, and quatertetrathiafulvalenes have been synthesized using cross- and homocoupling reactions of tetrathiafulvalenylzinc derivatives; the tetracation-tetraradical derived from the helical tetrathiafulvalene tetramer exhibits an intramolecular association of the terminal cation-radicals.