Indentation-Induced Selective Growth of Carbon Nanotubes

Indentation-Induced Selective Growth of Carbon Nanotubes
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压痕诱导碳纳米管的选择性生长

DOI:
10.1143/jjap.45.l800
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发表时间:
2006
期刊:
影响因子:
--
通讯作者:
S. Nishimura
S. Nishimura
中科院分区:
--
文献类型:
--
作者:
T. Yasui;S. Nishimura

文献摘要

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采用催化-乙醇化学气相沉积(CVD)方法,在Co(8 nm)/Si衬底上,于700 ~ 900 °C下沉积10 min,在压痕区选择性生长了半导体碳纳米管(CNTs)。压痕过程中产生的局部压力形成亚稳态Si,抑制Co/Si结合,导致Co聚集,并作为压痕内CNT生长的催化剂。扫描电子显微镜(SEM)和拉曼光谱证实,碳纳米管是单壁纳米管或单壁纳米管束,并且这些质量在每个凹痕之间是均匀的。
Semiconductor carbon nanotubes (CNTs) have been selectively grown in an indented area formed on Co (8 nm)/Si substrates by catalytic-ethanol chemical vapor deposition (CVD) at 700 to 900 °C for 10 min. The local pressure caused by the indentation process formed metastable Si, inhibited Co/Si combinations, caused Co aggregation, and acted as a catalyst for CNT growth within indents. The CNTs were single-walled nanotubes or bundle of them, and those qualities were uniform between each of the indents, as confirmed by the scanning-electron microscopy (SEM) and Raman spectra.