Amino-sugar modular ligands-useful cores for the formation of asymmetric copper 1,4-addition catalysts.
Amino-sugar modular ligands-useful cores for the formation of asymmetric copper 1,4-addition catalysts.
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DOI：
10.1039/b813137f
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发表时间：
2008-11
影响因子：
4.9
通讯作者：
Antonella De Roma;F. Ruffo;S. Woodward
中科院分区：
文献类型：
--
作者：
Antonella De Roma;F. Ruffo;S. Woodward
由商业N-乙酰葡糖胺快速合成的模块膦配体在ZnR（2）与线性脂肪族烯酮的铜（i）催化的1，4-加成中非常有效（87- 95%ee）。
Modular phosphine ligands, synthesised rapidly from commercial N-acetylglucosamine, are very effective in copper(i)-catalysed 1,4-additions of ZnR(2) to linear aliphatic enones (87-95% ee).