Frontiers in crystal engineering
Frontiers in crystal engineering
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DOI：
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发表时间：
2006
影响因子：
4.8
通讯作者：
E. Tiekink;J. Vittal
中科院分区：
文献类型：
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作者：
E. Tiekink;J. Vittal
贡献者名单。前言。1。晶体工程策略在无溶剂反应中的应用：走向超分子绿色化学。1导论。1氢键加合物的机械化学制备。1共价键的机械诱导形成。两性离子的无溶剂化学。1结束语。1确认。引用。2。药物共晶晶体工程。多态的起源是什么？多态在共晶中普遍存在吗？什么是药物共晶？4结论。5致谢。引用。3。模板控制的固态合成：分子固体中共价捕获的一般形式。1引言。2使用线性模板控制反应性。模板控制固态反应性。4 .有机状态下的靶向有机合成。5其他线性模板。6总结与展望。引用。4。非共价键的相互作用：晶体结构对分子结构的影响。1引言。2第二球配位。3 .软协调环境。5 .分子构象。6结论。引用。5。卤化异芳包合物体系的结晶工程。1绪论。2芳边边C-H…N二聚体。杂原子-1,3-环相互作用。分子笔结构。5卤化边-边相互作用。6 -卤二聚体（PHD）相互作用。分子砖、球体和网格。9致谢。引用。6。超分子聚集的空间控制：晶体工程中的设计元素？2羧酸二有机锡。3羧酸三有机锡。4二元锌黄药。二硫代磷酸锌的联吡啶加合物。6二硫代氨基甲酸汞。7二元铋黄药。8结论与展望。引用。7。将分子宿主纳入网络结构。1绪论。2 CTV的氢键结构。3配位聚合物。延伸臂CTV衍生物及其配位聚合物。6致谢。引用。8。互穿网络。1简介。2符号。31一维网络。4张二维网。5张3d网。不寻常的相互渗透。7 .相互渗透的后果。8 Self-penetration。纠缠而不互穿。10的结论。引用。9。基于桨轮双核四羧酸构建块的结构与功能工程。1导论。2合成策略。3基于预组织构建块的架构工程。基于预组织构件的导电性和磁性。5 .基于预组织和原位构建块的多孔性。6结论与展望。引用。10。指导和维持配位分子结构的超分子相互作用。1导论。2由氢键相互作用组装的分子结构。3 .通过…4亲金属相互作用。5结束语和展望。6确认。引用。11。配位聚合物中氢键对结构定向的影响。1引言。2一种新型氰化镉网络。镧系元素的二羟基苯醌和氯苯酸衍生物。阴离子金属-碳酸盐网络。6结论。引用。12。氢键配位聚合物结构。1导论。2氢键三维网络到三维配位聚合物网络结构的热脱水固态超分子转化。3 .可转换固态超分子转化。4热脱水作用下螺旋配位聚合物结构向三维配位网络结构的固相转化。手性中心对配位聚合物螺旋度的影响。6 C=O的后果……交互。7 .超分子异构。8星形通道和六边形菱形拓扑结构。9阶梯状一维配位聚合物内部的氢键螺旋水分子。[Zn(OAc)2(m-bpe)]. 2h2o中含环（H2O）4的氢键聚轮烷类结构。11摘要。12致谢。参考文献。索引。
List of Contributors. Foreword. 1. Applications of Crystal Engineering Strategies in Solvent-free Reactions: Toward a Supramolecular Green Chemistry. 1 Introduction. 1 Mechanochemical preparation of Hydrogen-Bonded Adducts. 1 Mechanically induced formation of covalent bonds. 1 The solvent-free chemistry of the zwitterion. 1 Concluding remarks. 1 Acknowledgements. References. 2. Crystal Engineering of Pharmaceutical Co-crystals. 1 Introduction. 2 What is the origin of polymorphism and is it prevalent in co-crystals?. 3 What is the pharmaceutical co-crystal?. 4 Conclusions. 5 Acknowledgements. References. 3. Template-controlled Solid-state Synthesis: Toward a General Form of Covalent Capture in Molecular Solids. 1 Introduction. 2 Controlling reactivity using linear templates. 3 Template-controlled solid-state reactivity. 4 Target-oriented organic synthesis in the organic state. 5 Other linear templates. 6 Summary and outlook. References. 4. Interplay of Non-covalent Bonds: Effect of Crystal Structure on Molecular Structure. 1 Introduction. 2 Second-sphere coordination. 3 Soft coordination environments. 4 Speciation. 5 Molecular conformation. 6 Conclusions. References. 5. Crystal Engineering of Halogenated Heteroaromatic Clathrate Systems. 1 Introduction. 2 Aromatic edge-edge C-H...N dimers. 3 Heteroatom-1,3-peri interactions. 4 Molecular pen structures. 5 Halogenated edge-edge interactions. 6 Pi-halogen dimer (PHD) interactions. 7 Molecular bricks, spheres and grids. 8 Conclusions. 9 Acknowledgements. References. 6. Steric Control over Supramolecular Aggregation: A Design Element in Crystal Engineering? 1 Introduction. 2 Diorganotin carboxylates. 3 Triorganotin carboxylates. 4 Binary zinc xanthates. 5 Bipyridine adducts of zinc dithiophosphates. 6 Binary mercury dithiocarbamates. 7 Binary bismuth xanthates. 8 Conclusions and Outlook. 9 Acknowledgements. References. 7. Incorporating Molecular Hosts into Network Structures. 1 Introduction. 2 Hydrogen-bonded structures with CTV. 3 Coordination polymers. 4 Extended-arm CTV derivatives and their coordination polymers. 5 Conclusions. 6 Acknowledgements. References. 8. Interpenetrating Networks. 1 Introduction. 2 Notation. 3 1-D nets. 4 2-D nets. 5 3-D nets. 6 Unusual interpenetration. 7 Consequences of interpenetration. 8 Self-penetration. 9 Entangled but not interpenetrating. 10 Conclusions. References. 9. Architecture and Functional Engineering Based on Paddlewheel Dinuclear Tetracarboxylate Building Blocks. 1 Introduction. 2 Synthetic strategy. 3 Architecture engineering based on preorganized building blocks. 4 Conductive and magnetic properties based on preorganized building blocks. 5 Porous properties based on preorganized and in situ building blocks. 6 Conclusion and outlook. References. 10. Supramolecular Interactions in Directing and Sustaining Coordination Molecular Architectures. 1 Introduction. 2 Molecular architectures assembled by hydrogen-bonding interactions. 3 Molecular architectures assembled VIA ... Interactions. 4 Metallophilic interactions. 5 Concluding remarks and outlooks. 6 Acknowledgements. References. 11. The Structure-directing Influence of Hydrogen Bonding in Coordination Polymers. 1 Introduction. 2 A novel cadmium cyanide network. 3 Dihydroxybenzoquinone and Chloranilic acid derivatives of Lanthanides. 4 A stable zinc saccharate network. 5 Anionic metal-carbonate networks. 6 Conclusions. References. 12. Hydrogen-bonded Coordination Polymeric Structures. 1 Introduction. 2 Solid-state supramolecular transformation of hydrogen-bonded 3-D network to 3-D coordination polymetric network structures by thermal dehydration. 3 Interconvertible solid-state supramolecular transformation. 4 Solid-state transformation of a helical coordination polymetric structure to a 3-D coordination network structure by thermal dehydration. 5 Influence of chiral centers on the helicity of the coordination polymers. 6 Consequences of C=O... interactions. 7 Supramolecular isomerism. 8 Starlike channels and hexagonal diamondoid topology. 9 Hydrogen-bonded helical water molecules inside a staircase 1-D coordination polymer. 10 Hydrogen-bonded polyrotaxane-like structure containing cyclic (H2O)4 in [Zn(OAc)2(m-bpe)].2H2O. 11 Summary. 12 Acknowledgements. References. Index.