One-dimensional hydrogen bonding networks of bis-hydroxylated diamantane formed inside double-walled carbon nanotubes.
One-dimensional hydrogen bonding networks of bis-hydroxylated diamantane formed inside double-walled carbon nanotubes.
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DOI：
10.1039/c7cc09832d
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发表时间：
2018-04
影响因子：
4.9
通讯作者：
Y. Nakanishi;H. Omachi;N. Fokina;P. Schreiner;Jonathan Becker;J. Dahl;R. Carlson;H. Shinohara
中科院分区：
文献类型：
--
作者：
Y. Nakanishi;H. Omachi;N. Fokina;P. Schreiner;Jonathan Becker;J. Dahl;R. Carlson;H. Shinohara
1，6-双（羟甲基）金刚烷在双壁碳纳米管内自发排列。包封的分子通过氢键在双壁碳纳米管内形成一维网络，与未官能化的金刚烷相比，氢键导致高度致密的填充。通过功能化提高前驱体的包封率是制备新型一维材料的关键。
1,6-Bis(hydroxymethyl)diamantane spontaneously aligns inside double-walled carbon nanotubes. The encapsulated molecules form a one-dimensional network within the double-walled carbon nanotubes through hydrogen bonding that leads to a highly dense filling as compared to unfunctionalized diamantane. Improving the encapsulation yields of precursors via functionalization is crucial to prepare novel one-dimensional materials.