Stabilisation of a highly reactive bis(mu-oxo)dicopper(III) species at room temperature by electronic and steric constraint of an unconventional nitrogen donor ligand.
Stabilisation of a highly reactive bis(mu-oxo)dicopper(III) species at room temperature by electronic and steric constraint of an unconventional nitrogen donor ligand.
复制标题
通过非常规氮供体配体的电子和空间约束在室温下稳定高反应性双(mu-oxo)二铜(III)物质。
作者:
S. Herres‐Pawlis;S. Binder;A. Eich;Roxana Haase;B. Schulz;G. Wellenreuther;G. Henkel;M. Rübhausen;W. Meyer
Herein we present an innovative combination of EXAFSspectroscopy and resonant Raman scattering for the charac-terisation of the ground state and structural dynamics of athermally stable binuclear bisACHTUNGRE(m-oxo) dicopperACHTUNGRE(III) species.Peralkylated bis(guanidine)-based ligands are used in thesynthesis of this compound.
影响因子:
5.6
作者:
Cuff, ME;Miller, KI;Hendrickson, WA
通讯作者:
Hendrickson, WA
影响因子:
16.6
作者:
Maiti, Debabrata;Lee, Dong-Heon;Karlin, Kenneth D.
通讯作者:
Karlin, Kenneth D.