Pentacoordinate organoantimony compounds that isomerize by turnstile rotation.
Pentacoordinate organoantimony compounds that isomerize by turnstile rotation.
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DOI：
10.1021/ja808113q
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发表时间：
2009-03
影响因子：
15
通讯作者：
S. Matsukawa;Hideaki Yamamichi;Yohsuke Yamamoto;K. Ando
中科院分区：
文献类型：
--
作者：
S. Matsukawa;Hideaki Yamamichi;Yohsuke Yamamoto;K. Ando
合成了具有新的刚性三齿配体的五配位锑化合物（锑硼烷）的两种立体异构体，并发现异构化是通过旋转门旋转（TR）机制进行的，其中三齿配体为三组，两个单齿配体为一对。
Two stereoisomers of pentacoordinate antimony compounds (stiboranes) with a new rigid tridentate ligand were synthesized, and the isomerization was found to proceed by the turnstile rotation (TR) mechanism with the tridentate ligand as a trio and the two monodentate ligands as a pair.