BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response
BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response
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DOI：
10.1021/ja9030566
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发表时间：
2009-07-15
影响因子：
15
通讯作者：
Mao, Jiang-Gao
中科院分区：
文献类型：
--
作者：
Sun, Chuan-Fu;Hu, Chun-Li;Mao, Jiang-Gao
通过将具有d(0)电子构型的Nb5+与含碘酸根的色调对阴离子相结合，合成了一种新的倍频材料BanBO(IO3)(5)。它具有非常大的倍频响应(类似于KH_2PO_4的14倍，类似于α-SiO_2的660倍)，并且是相匹配的，该材料具有高的热稳定性和宽的透明区域。
By combination of Nb5+ (having a d(0) electronic configuration) and the tone-pair-containing iodate anion, a new SHG material, BaNbO(IO3)(5), has been prepared. It exhibits a very large SHG response (similar to 14 times that of KH2PO4 and similar to 660 times that of alpha-SiO2) and is phase-matchable, The material has high thermal stability and a wide transparent region.