Dications Based on a Hydrotris(phosphonio)borate Skeleton
Dications Based on a Hydrotris(phosphonio)borate Skeleton
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基于Hydrotris(膦基)硼酸盐骨架的阳离子
DOI：
10.1002/anie.198810711
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发表时间：
1988
影响因子：
--
通讯作者：
G. Müller
中科院分区：
文献类型：
--
作者：
H. Schmidbaur;T. Wimmer;G. Reber;G. Müller
前两个具有[HBP3]2⊕骨架(1和2)--硼原子被三个磷中心和一个氢原子包围--被分离出来作为二溴化物，并通过X射线结构分析进行了表征。这两种盐对空气和水分的稳定性是显著的。在碱性D2O中，硼键合的H原子被交换为D原子。
The first two dications having a [HBP 3] 2⊕ framework (1 and 2)—the boron atom is surrounded by three phosphonium centers and a hydrogen atom—were isolated as dibromides and characterized by X‐ray structure analysis. The stability of the two salts toward air and moisture is remarkable. The boron‐bonded H atom is exchanged for a D atom in alkaline D 2 O.