The First Lithium Difluorophosphate LiPO2F2 with a Neutral Polytetrahedral Microporous Architecture
The First Lithium Difluorophosphate LiPO2F2 with a Neutral Polytetrahedral Microporous Architecture
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第一个具有中性多四面体微孔结构的二氟磷酸锂LiPO2F2
DOI：
10.1039/c8cc10158b
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发表时间：
2019
期刊：
影响因子：
--
通讯作者：
Shilie Pan
中科院分区：
文献类型：
--
作者：
Guopeng Han;Ying Wang;Hao Li;Zhihua Yang;Shilie Pan
在此，我们提出了第一个二氟磷酸锂LiPO2F2表现出独特的多面体微孔结构。独特的氟配位环境和交错的[LiO2]3−直链产生了中性孔框架，该框架具有沿着晶体学c轴的10元环通道。已采用各种测量系统地表征LiPO2F2。这项工作通过探索迷人的二氟磷酸盐，为磷酸盐化学的结构和功能多样性做出了贡献。
Herein, we present the first lithium difluorophosphate LiPO2F2 exhibiting a unique polytetrahedral microporous architecture. The unique fluorine coordination environments and interlaced [LiO2]3− straight chains give rise to the neutral pore framework with a 10- membered ring channel along the crystallographic c axis. A variety of measurements have been adopted to systemically characterize LiPO2F2. This work contributes to the structural and functional diversity of phosphate chemistry by the exploration of fascinating difluorophosphates.