Ligand Effects on the Stereochemical Outcome of Suzuki-Miyaura Couplings
Ligand Effects on the Stereochemical Outcome of Suzuki-Miyaura Couplings
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DOI：
10.1021/jo300437t
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发表时间：
2012-04-20
影响因子：
3.6
通讯作者：
Lipshutz, Bruce H.
中科院分区：
文献类型：
--
作者：
Lu, Guo-Ping;Voigtritter, Karl R.;Lipshutz, Bruce H.
与各种Pd催化剂相关的配体在确定硼酸和Z-烯基卤化物之间的交叉偶联的立体化学中起着至关重要的作用。已发现钯上的配体在温和条件下以高产率得到所需产物，在大多数情况下，所述产物保留其Z-烯烃几何形状。
The ligands associated with various Pd catalysts play a crucial role in determining the stereochemistry of cross-couplings between boronic acids and Z-alkenyl halides. A ligand on palladium has been found that leads to the desired products under mild conditions and in high yields that, in most cases, retain their Z-olefin geometry.