Synthesis, Structure and Physicochemical Properties of a Saddle-Distorted Porphyrin with a Peripheral Carboxyl Group
Synthesis, Structure and Physicochemical Properties of a Saddle-Distorted Porphyrin with a Peripheral Carboxyl Group
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外围羧基鞍形畸变卟啉的合成、结构及理化性质
DOI：
10.1142/s1088424611003379
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发表时间：
2011
影响因子：
1.5
通讯作者：
T.Kojima
中科院分区：
文献类型：
--
作者：
M.Sankar;T.Ishizuka;Z.Wang;T.Ma;M.Shiro;T.Kojima
A saddle-distorted porphyrin bearing a carboxyl group as a hydrogen-bonding site on ameso-phenyl group was synthesized and characterized. A supramolecular structure with intermolecular hydrogen bonding was revealed by X-ray diffraction analysis. The effects of the peripheral carboxyl group on the physicochemical properties of the porphyrin as well as on self-assembly were investigated by spectroscopic measurements in solutions. The redox properties of the porphyrin and its Zn(II) complex were also studied by electrochemical measurements and their application to dye-sensitized solar cells was examined.
