Multianvil high-pressure synthesis of Dy4B6O15:: The first oxoborate with edge-sharing BO4 tetrahedra
Multianvil high-pressure synthesis of Dy4B6O15:: The first oxoborate with edge-sharing BO4 tetrahedra
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DOI：
10.1021/ja017691z
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发表时间：
2002-08-14
影响因子：
15
通讯作者：
von der Eltz, B
中科院分区：
文献类型：
--
作者：
Huppertz, H;von der Eltz, B
在所有已知的氧代硼酸盐中，B 0 3和B 0 4基团的连接通过共同的角进行。在这里，我们提出了高压/高温合成Dy 4 B6 O 15，这是第一个显示共边BO 4四面体的氧代硼酸盐。
In all known oxoborates the linkage of BO3and BO4groups is performed via common corners. Here we present the high-pressure/high-temperature synthesis of Dy4B6O15, which is the first oxoborate exhibiting edge-sharing BO4tetrahedra.