Optical microscopy study of zeolite-dye composite materials

Optical microscopy study of zeolite-dye composite materials
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DOI:
10.1016/j.micromeso.2006.12.010
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发表时间:
2007-04
影响因子:
5.2
通讯作者:
S. Hashimoto;H. Moon;K. B. Yoon
S. Hashimoto;H. Moon;K. B. Yoon
中科院分区:
材料科学2区
文献类型:
--
作者:
S. Hashimoto;H. Moon;K. B. Yoon

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我们应用共聚焦荧光显微镜研究了荧光染料在微米级沸石晶体中的空间分布和化学反应。直接观察了染料渗透到棒状沸石L晶体和八面体沸石X晶体的孔中。几个显着的性能的染料在沸石主机,只能观察到的应用程序的显微镜方法,证明。此外,给出了甲基紫精MV ~(2+)对Ru(bpy)~(32+)嵌入沸石X和Y中的发光猝灭反应的空间分辨图像。
We applied confocal fluorescence microscopy to investigate the spatial distribution and chemical reactions of fluorescent dyes incorporated in micrometer-sized zeolite crystals. The penetration of dyes into the pores of rod-like zeolite L crystals and of octahedron-shaped zeolite X crystals was visualized directly. A few remarkable properties of dyes in the zeolite hosts, only observable by the application of the microscopy method, are demonstrated. Furthermore, a space-resolved image is given for the luminescence quenching reaction of ruthenium trisbipyridine complex, Ru(bpy)32+, incorporated into zeolites X and Y by methyl viologen, MV2+.