The Faraday Rotation of Allowed Transitions: Charge-Transfer Transitions in K3Fe(CN)6
The Faraday Rotation of Allowed Transitions: Charge-Transfer Transitions in K3Fe(CN)6
复制标题
允许跃迁的法拉第旋转：K3Fe(CN)6 中的电荷转移跃迁
DOI：
10.1021/ic50034a003
复制
发表时间：
1965
影响因子：
4.6
通讯作者：
P. Stephens
中科院分区：
文献类型：
--
作者：
P. Stephens
Shashoua 2a和Briat 2b最近通过K_3Fe-（CN）_6的两个最低电荷转移带测量了其磁旋光色散（MORD）。本文的目的是指出，他们的结果表明，这些带的最新分配是不正确的，并在一般情况下，证明允许跃迁的MORD如何提供有关所涉及的状态的对称性的信息。在沿着z轴的纵向磁场H中，跃迁a-*-j对各向同性物质摩尔磁转动的贡献为6· 6 [<p（a-j）]=-
Shashoua2a and Briat2b have recently measured the magnetic optical rotation dispersion (MORD) of K3Fe-(CN) e through its two lowest charge-transfer bands. The purpose of this note is to point out that their re-sults show the latest assignment ofthese bands3· 4 to be incorrect and, in general, to demonstrate howthe MORD of allowed transitions provides information about the symmetries of the states involved. The contribution of the transition a—*-j to the molar magnetic rotation of an isotropic substance in a longitudinal magnetic field, H, along the z axis is6· 6 [<¡ p (a—j)]=—