Phase diagram of high Tc Pb(In1/2Nb1/2)O3-PbTiO3 ceramics

Phase diagram of high Tc Pb(In1/2Nb1/2)O3-PbTiO3 ceramics
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DOI:
10.1016/j.jeurceramsoc.2005.03.076
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发表时间:
2005-11
影响因子:
5.7
通讯作者:
C. Augier;M. Phamthi;H. Dammak;P. Gaucher
C. Augier;M. Phamthi;H. Dammak;P. Gaucher
中科院分区:
材料科学1区
文献类型:
--
作者:
C. Augier;M. Phamthi;H. Dammak;P. Gaucher

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采用热锻法和热晶生长法合成了致密的(1−x)Pb(In1/2Nb1/2)O 3-xPbTiO 3(PIN-PT)陶瓷。用X射线衍射法和介电测量研究了(1−x)PIN-xPT相图。当PT含量较低时,相界区域介于三方相区和较高含量时的四方相区之间,即在0.34-0.39X范围内。在室温下,当x=0.37时,观察到四方相和可能的单斜相的混合物。
Dense (1−x)Pb(In1/2Nb1/2)O3–xPbTiO3(PIN–PT) ceramics were synthesised by hot forging and thermal grain growth. (1−x)PIN–xPT phase diagram was investigated by X-ray diffraction and dielectric measurements. The morphotropic phase boundary zone was found to be between a rhombohedral phase region for low PT contents and a tetragonal phase region for high PT contents, i.e. in the 0.34–0.39x range. A mixture of tetragonal and probably monoclinic phases was observed for x=0.37 at room temperature.