Analysis of Fischer‐Tropsch by‐product waters by gas chromatography
Analysis of Fischer‐Tropsch by‐product waters by gas chromatography
复制标题
用气相色谱法分析费托副产物水
DOI：
--
复制
发表时间：
1994
期刊：
影响因子：
--
通讯作者：
C. M. White
中科院分区：
文献类型：
--
作者：
R. Anderson;C. M. White
本文描述了一种测定费托副产物水中有机成分的定量技术。衍生化键合极性毛细管柱上的程序升温气相色谱可提供所需的分离，从而可以对各个化合物进行可靠的定量。提出了一项初步的组合气相色谱-质谱调查，用于识别费托副产品水中存在的成分。 58 个已识别组分的洗脱顺序已制成表格。在典型的费托副产物水中鉴定出的成分包括 C1-C9 直链和支链醇、C3C8 酮、C2C6 羧酸和 C2C4 直链醛。
This paper describes a quantitative technique for the determination of organic constituents in Fischer-Tropsch by-product waters. Temperature-programmed gas chromatography on derivatized bonded polar capillary columns provides the required separation that permits reliable quantitation of individual compounds. A preliminary combined gas chromatographic–mass spectrometric survey to identify the components present in Fischer-Tropsch by-product waters is presented. The elution order of 58 identified components is tabulated. Components identified in a typical Fischer-Tropsch by-product water include C1–C9 linear and branched alcohols, C3C8 ketones, C2C6 carboxylic acids, and C2C4 linear aldehydes.