Electrodeposition of Coherent Deposits of Refractory Metals V . Mechanism for the Deposition of Molybdenum from a Chloride Melt
Electrodeposition of Coherent Deposits of Refractory Metals V . Mechanism for the Deposition of Molybdenum from a Chloride Melt
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DOI：
10.1149/1.2426648
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发表时间：
1967-06
影响因子：
3.9
通讯作者：
S. Senderoff;G. W. Mellors
中科院分区：
文献类型：
--
作者：
S. Senderoff;G. W. Mellors
After observing an irreversible step in the electrode process in all cases of coherent deposition of metals from molten fluorides, a chronopotentiometric study of the KC1-LiC1-K3MoC16 system which produces coherent molybdenum deposits was undertaken. It was found that in this case also, the electrode process was irreversible at 600~ a temperature at which coherent deposits are produced, and became more reversible as the temperature increased. The irreversible behavior of the electrode and the decrease of bath stability with decrease in concentration of molybdenum could be explained on the basis of the following mechanism slow [Mo2C19]-s (1)+ 3C1-(1)~, 2 [MoC18]-3 (1)(A)
