Facile synthesis of a ruthenium assembly and its application for light-driven oxidation of alcohols in water
Facile synthesis of a ruthenium assembly and its application for light-driven oxidation of alcohols in water
复制标题
钌组装体的简便合成及其在水中醇的光驱动氧化中的应用
DOI：
10.1039/c3cc00305a
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发表时间：
2013-01-01
影响因子：
4.9
通讯作者：
Fu, Wen-Fu
中科院分区：
文献类型：
--
作者：
Chao, Duobin;Fu, Wen-Fu
以90%的产率合成了一种含有两个捕光片段[Ru（tpy）（2）]（2+）和一个催化单元[Ru（tpy）（bpy）Cl]（+）的超分子组装体，并在室温下以[Co（NH3）（5）Cl] 2-为牺牲氧化剂光催化氧化醇类时表现出比相应的双分子体系更高的光催化产物选择性.
A supramolecular assembly containing two light harvesting fragments [Ru(tpy)(2)](2+) and one catalytic unit [Ru(tpy)(bpy)Cl](+) was synthesized in a facile manner in 90% yield, and exhibited high photocatalytic product-selectivity compared with the corresponding bimolecular system in the light-driven oxidation of alcohols using [Co(NH3)(5)Cl]Cl-2 as a sacrificial oxidant in water at room temperature.