Shedding light on hidden reaction pathways in radical polymerization by a porous coordination network
Shedding light on hidden reaction pathways in radical polymerization by a porous coordination network
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DOI：
10.1039/c1cc15053g
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发表时间：
2011-01-01
影响因子：
4.9
通讯作者：
Fujita, Makoto
中科院分区：
文献类型：
--
作者：
Inokuma, Yasuhide;Nishiguchi, Satoshi;Fujita, Makoto
含2-乙烯基三苯基的配位网络在高温下被AIBN处理，但空间分离完全抑制了乙烯基单体的自由基聚合，增强了隐藏的有氧氧化途径。
A coordination network comprising 2-vinyltriphenylene was treated with AIBN at a high temperature, but the radical polymerization of the vinyl monomer was completely suppressed by spatial separation and otherwise hidden aerobic oxidation pathways are enhanced.