Elucidation of the mechanism of titanocene-mediated epoxide opening by a combined experimental and theoretical approach
Elucidation of the mechanism of titanocene-mediated epoxide opening by a combined experimental and theoretical approach
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DOI：
10.1002/anie.200504176
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发表时间：
2006-01-01
影响因子：
16.6
通讯作者：
Keller, F
中科院分区：
文献类型：
--
作者：
Daasbjerg, K;Svith, H;Keller, F
方案中涉及二聚体的氧化和氧化的二聚体(蓝色墨水)的碎裂的部分仅适用于R=Me。在这种情况下，循环伏安图与之前观察到的锌-Cp2TiCl2的二聚体物种的存在是一致的。在不同浓度和扫频下记录的1S伏安图如图1S和2S所示。
The part of the scheme involving the oxidation of the dimer and the fragmentation of the oxidized dimer (blue ink) applies only for R= Me. In this case the cyclic voltammograms are consistent with the presence of a dimeric species as it was observed previously for Zn-Cp2TiCl2. 1S Voltammograms recorded at different concentrations and sweep rates are shown in Figures 1S and 2S.