Selenacalix[3]triazines: synthesis and host-guest chemistry.

Selenacalix[3]triazines: synthesis and host-guest chemistry.
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DOI:
10.1039/c1cc15473g
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发表时间:
2012-01
影响因子:
4.9
通讯作者:
Joice Thomas;Wim Van Rossom;K. Van Hecke;L. Van Meervelt;M. Smet;W. Maes;W. Dehaen
Joice Thomas;Wim Van Rossom;K. Van Hecke;L. Van Meervelt;M. Smet;W. Maes;W. Dehaen
中科院分区:
化学2区
文献类型:
--
作者:
Joice Thomas;Wim Van Rossom;K. Van Hecke;L. Van Meervelt;M. Smet;W. Maes;W. Dehaen

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杂杯芳烃系列(N/O/S)已扩大与硒桥环三聚大环。通过一锅亲核取代反应合成了硒杂杯[3]三嗪类化合物,它们具有独特的超分子结构。N三齿结合口袋能够同时配位铜离子和阴离子。
The heteracalixarene series (N/O/S) has been expanded with Se-bridged cyclotrimeric macrocycles. Selenacalix[3]triazines were synthesized by convenient one-pot nucleophilic aromatic substitution reactions and they showed peculiar supramolecular features. The N tridentate binding pocket was capable of coordinating both copper ions and anions.