Regioselective hydroboration-oxidation and -amination of fluoro-substituted styrenes

Regioselective hydroboration-oxidation and -amination of fluoro-substituted styrenes
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DOI:
10.1016/j.jfluchem.2006.06.013
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发表时间:
2006-09-01
影响因子:
1.9
通讯作者:
O'Donnell, Martin J.
O'Donnell, Martin J.
中科院分区:
化学4区
文献类型:
--
作者:
Ramachandran, P. Veeraraghavan;Madhi, Sateesh;O'Donnell, Martin J.

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Hydroboration of fluorinated styrenes with common hydroborating agents results in polymerization. However, regioselective hydroboration has been achieved by utilizing iodoborane-dimethyl sulfide. A series of fluorinated beta-phenethyl alcohols and amines were synthesized via this methodology. (c) 2006 Elsevier B.V. All rights reserved.