The action of ammonia on benzoin
The action of ammonia on benzoin
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DOI：
10.1021/jo01227a005
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发表时间：
1937-09-01
影响因子：
3.6
通讯作者：
Jelling, M
中科院分区：
文献类型：
--
作者：
Davidson, D;Weiss, M;Jelling, M
本文研究了乙酸中的氨对安息香的作用。 6 在此介质中，发现安息香主要产生阿马隆 (I) 和 2-甲基-4, 5-二苯基乙恶啉 (II) 以及二氢阿马隆。通过研究其他酸，特别是甲酸，并进一步测试乙酸中的氨对安息香酯的作用，对这一反应的机理有了一些了解。后者
The present paper deals with an examination of the action of ammonia in acetic acid on benzoin. 6 In this medium it is found that benzoin yields mainly amarone(I) and 2-methyl-4, 5-diphenylglyoxaline (II) together with dihydroamarone. Some light is thrown on the mechanism of this reaction by studying other acids particularly formic, and, further by test-ing the action of ammonia in acetic acid on esters of benzoin. This latter