Potentially biodegradable polymers based on α- or β-pinene and sugar derivatives or styrene, obtained under normal conditions and on microwave irradiation
Potentially biodegradable polymers based on α- or β-pinene and sugar derivatives or styrene, obtained under normal conditions and on microwave irradiation
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DOI：
10.1002/ejoc.200600890
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发表时间：
2007-03-01
影响因子：
2.8
通讯作者：
Ramos, Ana Maria
中科院分区：
文献类型：
--
作者：
Barros, Maria Teresa;Petrova, Krasimira T.;Ramos, Ana Maria
研究了α-和β-蒎烯的均聚及其与苯乙烯和七-O-苄基-6 '-O-甲基丙烯酰蔗糖（BMS）在AIBN作为自由基引发剂存在下，在甲苯中或无溶剂中，在80 ℃，常压和合成微波炉中的共聚反应。研究了反应条件、单体结构和共聚单体的初始比例对最终共聚物性能的影响，每个共聚物含有两种天然产物。发现了在短反应时间和温和条件下用微波辐射合成聚（β-蒎烯）、聚（α-蒎烯-共-苯乙烯）和聚（β-蒎烯-共-苯乙烯）的新方法（（C）Wiley-VCH Verlag GmbH & Co. KGaA，69451魏因海姆，德国，2007）。
The homopolymerisation of alpha- and beta-pinene and their copolymerisation with styrene and hepta-O-benzyl-6'-O-methacryloyl-sucrose (BMS) have been examined in the presence of AIBN as free-radical initiator, either in toluene or without solvent at 80 degrees C at normal pressure and also in a synthetic microwave oven. A study of the effect of the reaction conditions, the monomer structure and the initial ratio of the comonomers on the properties of the final copolymers, each containing two natural products, has been carried out. A new procedure for synthesising poly(P-pinene), poly(alpha-pinene-co-styrene), and poly(beta-pinene-co-styrene) in short reaction times and under mild conditions with microwave irradiation was found. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).