Transition-metal-catalyzed dehydrocoupling: A convenient route to bonds between main-group elements
Transition-metal-catalyzed dehydrocoupling: A convenient route to bonds between main-group elements
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DOI：
10.1002/chem.200600981
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发表时间：
2006-11-24
影响因子：
4.3
通讯作者：
Manners, Ian
中科院分区：
文献类型：
--
作者：
Clark, Timothy J.;Lee, Kajin;Manners, Ian
过渡金属催化的脱氢偶联反应作为形成主族元素-元素键的合成方法的发展为传统途径如盐作为盐复分解/消除型反应提供了越来越有吸引力和方便的替代方案。自20世纪80年代初第一次报道的例子以来，这一领域迅速扩大，扩展到各种各样的金属介导的homelands和heterelands键形成过程。这一新化学在分子和高分子合成、材料科学、储氢以及有机底物的转移氢化等方面的应用正引起人们越来越多的关注。这篇概念文章概述了这一新兴领域，重点介绍了最近的成果。
The development of transition-metal-catalyzed dehydrocoupling reactions as a synthetic method for the formation of main-group element-element bonds provides an increasingly attractive and convenient alternative to traditional routes such as salt metathesis/elimination-type reactions. Since the first reported examples in the early 1980s, there has been a rapid expansion of this field, with extensions to a wide variety of metal-mediated homonuclear and heteronuclear bond-forming processes. Applications of this new chemistry in molecular and polymer synthesis, materials science, hydrogen storage and the transfer hydrogenation of organic substrates are attracting growing attention. An overview of this emerging area is presented in this Concepts article with a focus on recent results.