Highly regioselective nucleophilic carbon-carbon bond formation on furans and thiophenes initiated by Pumerer-type reaction
Highly regioselective nucleophilic carbon-carbon bond formation on furans and thiophenes initiated by Pumerer-type reaction
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DOI：
10.1021/ol0484310
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发表时间：
2004-10-14
期刊：
影响因子：
5.2
通讯作者：
Kita, Y
中科院分区：
文献类型：
--
作者：
Akai, S;Kawashita, N;Kita, Y
(图)在三氟乙酸酐存在下，(苯亚磺酰基)呋喃或-噻吩类化合物与碳亲核试剂发生反应，从而使碳官能团亲核安装在呋喃和噻吩基上，具有完全的区域选择性。
(GRAPHICS)The reactions of (phenyLsulfinyl)furans or -thiophenes with carbon nucleophiles in the presence of trifluoroacetic anhydride allowed the nucleophilic installation of carbon functional groups on the furan and thiophene nuclei with complete regioselectivity.