A Concise Account of Recent SN2′ Grignard Coupling Reactions in Organic Synthesis
A Concise Account of Recent SN2′ Grignard Coupling Reactions in Organic Synthesis
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DOI：
10.1055/s-2005-918455
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发表时间：
2005-11
期刊：
影响因子：
--
通讯作者：
A. Kar;N. Argade
中科院分区：
文献类型：
--
作者：
A. Kar;N. Argade
在过去的几十年里，关于控制烯丙基取代反应的化学选择性、区域选择性和立体选择性的研究已经在文献中有很好的记载，并且SN 2' Grignard偶联反应已经成为选择性碳-碳键形成的非常有力的工具。本文综述了这类特殊反应的合成进展。
Over the past few decades studies on controlling the chemo-, regio- and stereoselectivities of allylic substitution reactions have been well documented in the literature and the S N 2' Grignard coupling reaction has emerged as a very powerful tool in selective carbon-carbon bond formation. This review focuses on all the recent synthetic developments in this special class of reactions.