A bifunctional strategy towards experimentally (synthetically) attainable molecules with planar tetracoordinate carbons.

A bifunctional strategy towards experimentally (synthetically) attainable molecules with planar tetracoordinate carbons.
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DOI:
10.1039/b916594k
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发表时间:
2010-01
期刊:
Physical chemistry chemical physics : PCCP
影响因子:
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通讯作者:
Yan-Bo Wu;Jin Jiang;Hua Li;Zhongfang Chen;Zhi‐Xiang Wang
Yan-Bo Wu;Jin Jiang;Hua Li;Zhongfang Chen;Zhi‐Xiang Wang
中科院分区:
其他
文献类型:
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作者:
Yan-Bo Wu;Jin Jiang;Hua Li;Zhongfang Chen;Zhi‐Xiang Wang

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通过有效利用价电子和提供空间位阻保护的双功能策略,将具有双平面四配位碳(ptC)的C(2)Al(4)整体极小值推进到一类新的ptC分子,有望实现合成.
Bifunctional strategy, including efficiently utilizing valence electrons and offering steric protection, has been proposed to advance C(2)Al(4) global minimum with double planar tetracoordinate carbons (ptC) to a new family of ptC molecules which could be promising for synthetic realization.