Intermediates in the Rh-catalysed dehydrocoupling of phosphine-borane
Intermediates in the Rh-catalysed dehydrocoupling of phosphine-borane
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DOI：
10.1039/c2cc32696e
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发表时间：
2012-01-01
影响因子：
4.9
通讯作者：
Weller, Andrew S.
中科院分区：
文献类型：
--
作者：
Huertos, Miguel A.;Weller, Andrew S.
报道了以[Rh（COD）（2）][BAr_4F]为预催化剂，膦硼烷H_3B中心点（PBu_2 H）-Bu-t脱氢偶联制（HPBu_2BH_2 PBu_2BH_3）-Bu-t-Bu-t的活性物种、产物分布和催化循环.
Active species, product distributions and a suggested catalytic cycle are reported for the dehydrocoupling of the phosphine-borane H3B center dot(PBu2H)-Bu-t to give (HPBu2BH2PBu2BH3)-Bu-t-Bu-t using the [Rh(COD)(2)][BAr4F] pre-catalyst.