Thioketone-Directed Palladium(II)-Catalyzed C-H Arylation of Ferrocenes with Aryl Boronic Acids
Thioketone-Directed Palladium(II)-Catalyzed C-H Arylation of Ferrocenes with Aryl Boronic Acids
复制标题
硫酮引导的钯 (II) 催化二茂铁与芳基硼酸的 C-H 芳基化
DOI：
10.1002/anie.201711451
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发表时间：
2018-01-26
影响因子：
16.6
通讯作者：
You, Shu-Li
中科院分区：
文献类型：
--
作者：
Cai, Zhong-Jian;Liu, Chen-Xu;You, Shu-Li
A palladium(II)-catalyzed thioketone-chelation-assisted direct C-H arylation of ferrocenes is described. With thioketone as an efficient directing group, various monoaryl- and diaryl-substituted thiocarbonylferrocenes were obtained by palladium-catalyzed direct C-H functionalization in high yields under mild and base-free reaction conditions. Furthermore, the arylated thiocarbonylferrocene could undergo diverse transformations.
