Reaction of five-membered zirconacycloallenoids with the strong Lewis acid B(C6F5)3.

Reaction of five-membered zirconacycloallenoids with the strong Lewis acid B(C6F5)3.
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DOI：
10.1039/c4dt01137f
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发表时间：
2014-07
期刊：
Dalton transactions
影响因子：
4
通讯作者：
Georg Bender;C. Daniliuc;B. Wibbeling;G. Kehr;G. Erker
Georg Bender;C. Daniliuc;B. Wibbeling;G. Kehr;G. Erker
中科院分区：
化学2区
文献类型：
--
作者：
Georg Bender;C. Daniliuc;B. Wibbeling;G. Kehr;G. Erker

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两个烷基和芳基取代的五元锆环烯丙基化合物与B（C6 F5）3发生典型的σ-烷基茂金属反应，即Zr-C（sp（3））键断裂，生成两性离子（η（2）-联烯基）锆/烷基硼酸盐产物。两种产物均通过X射线晶体结构分析表征。
Two alkyl and aryl substituted five-membered zirconacycloallenoids underwent a typical σ-alkyl metallocene reaction with B(C6F5)3, namely cleavage of the Zr-C(sp(3)) bond with formation of zwitterionic (η(2)-allenyl)zirconium/alkylborate products. Both products were characterized by X-ray crystal structural analyses.