Progressive-convergent elucidation of stereochemistry in complex polyols. The absolute configuration of (-)-sagittamide A.
Progressive-convergent elucidation of stereochemistry in complex polyols. The absolute configuration of (-)-sagittamide A.
复制标题
复杂多元醇立体化学的渐进收敛阐明。
DOI：
10.1021/ja063735y
复制
发表时间：
2006
影响因子：
15
通讯作者：
Molinski,TadeuszF
中科院分区：
文献类型：
--
作者：
Lievens,SarahC;Molinski,TadeuszF
The absolute stereostructure of sagittamide A (1), aO-hexacetyl long-chain hexahydroxy-α,ω-dicarboxylic acid, was assigned using a progressive−convergent approach that integrates three powerful regimens for stereochemical analysis of acyclic natural products:J-based analysis,13C NMR universal database comparisons, and exciton coupling circular dichroism.
