Tertiary Hierarchical Complexity in Assemblies of Sulfur-Bridged Metal Chiral Clusters
Tertiary Hierarchical Complexity in Assemblies of Sulfur-Bridged Metal Chiral Clusters
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DOI：
10.1021/jacs.0c04764
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发表时间：
2020-08-26
影响因子：
15
通讯作者：
Robinson, Richard D.
中科院分区：
文献类型：
--
作者：
Han, Haixiang;Yao, Yuan;Robinson, Richard D.
跨多个长度尺度的有序三维结构的自组装（层次组装）对于生物分子的生命功能非常重要。人造生物材料和先进功能材料一直在追求从无机构建块创建类似的复杂结构。然而，目前的研究主要仅采用大型非反应性构件，例如金胶体。相比之下，硫桥过渡金属簇（
Self-assembly of three-dimensional structures with order across multiple length scales-hierarchical assembly-is of great importance for biomolecules for the functions of life. Creation of similar complex architectures from inorganic building blocks has been pursued toward artificial biomaterials and advanced functional materials. Current research, however, primarily employs only large, nonreactive building blocks such as Au colloids. By contrast, sulfur-bridged transition metal clusters (