Phosphinidene group-transfer with a phospha-Wittig reagent: a new entry to transition metal phosphorus multiple bonds
Phosphinidene group-transfer with a phospha-Wittig reagent: a new entry to transition metal phosphorus multiple bonds
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DOI：
10.1039/b910410k
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发表时间：
2009-01-01
影响因子：
4.9
通讯作者：
Mindiola, Daniel J.
中科院分区：
文献类型：
--
作者：
Kilgore, Uriah J.;Fan, Hongjun;Mindiola, Daniel J.
亚膦基-σ（4）-正膦试剂Me 3 P =PAr（Ar = 2，4，6-（Bu 3C 6 H2）-Bu-t和2，6-Mes（2）C（6）H（3））是末端亚膦基部分PAr到由锆和钒组成的前过渡金属的良好递送载体。
The phosphanylidene-sigma(4)-phosphorane reagents Me3P=PAr (Ar = 2,4,6-(Bu3C6H2)-Bu-t and 2,6-Mes(2)C(6)H(3)) are good delivery vehicles of the terminal phosphinidene moiety, PAr, to early-transition metals composed of zirconium and vanadium.