Shape-controlled synthesis of nanocarbons from resorcinol-formaldehyde nanopolymers using surfactant-templated vesicular assemblies
Shape-controlled synthesis of nanocarbons from resorcinol-formaldehyde nanopolymers using surfactant-templated vesicular assemblies
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DOI：
10.1016/j.carbon.2007.01.020
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发表时间：
2007-05-01
期刊：
影响因子：
10.9
通讯作者：
Kijma, Tsuyoshi
中科院分区：
文献类型：
--
作者：
Fujikawa, Daisuke;Uota, Masafumi;Kijma, Tsuyoshi
间苯二酚(R)和甲醛(F)在NaOH催化下聚合，以十六烷基三甲基溴化铵为核心模板剂，与1，3，5-三甲苯和叔丁醇(TBuOH)混合作为助表面活性剂，制备了RF聚合物/十六烷基三甲基铵复合纳米线和纳米球。纳米聚合物的碳化得到了直径为45-240 nm的微孔碳纳米线和直径为260-650 nm的纳米球。类似的但稍加修饰的反应成功地得到了直径约280 nm的单分散碳纳米球和直径约70 nm的单分散碳纳米线，其比表面积高达1777m(2)/g。该方法可进一步扩展到使用各种表面活性剂和助表面活性剂合成各种碳纳米材料。(C)2007爱思唯尔有限公司。保留所有权利。
The NaOH-catalyzed polymerization of resorcinol (R) and formaldehyde (F) confined to the vesicular assemblies of cetyltrimethy-ammonium bromide as a core template mixed with 1,3,5-trimethylbenzene and tert-butanol (tBuOH) as cosurfactants yielded RF polymer/cetyltrimethylammonium composite nanowires and nanospheres depending on the amount of tBuOH. Carbonization of the resulting nanpolymers led to microporous carbon nanowires of 45-240 nm diameter and nanospheres of 260-650 nm diameter. Similar but a little modified reactions successfully resulted in monodispersed carbon nanospheres of ca. 280 nm diameter as well as monodispersed carbon nanowires of ca. 70 nm diameter with a high surface area of 1777 m(2)/g. The present approach could be further extended to the synthesis of a wide range of carbon nanomaterials by using various surfactants and cosurfactants. (C) 2007 Elsevier Ltd. All rights reserved.