[(CO)3(PPH3)2OSAG(O2CCF3)] - A MODEL FOR AN INTERMEDIATE ON THE REACTION COORDINATE IN ELECTRON-TRANSFER
[(CO)3(PPH3)2OSAG(O2CCF3)] - A MODEL FOR AN INTERMEDIATE ON THE REACTION COORDINATE IN ELECTRON-TRANSFER
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DOI：
10.1002/anie.199207701
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发表时间：
1992-06-01
期刊：
影响因子：
--
通讯作者：
TROGLER, WC
中科院分区：
文献类型：
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作者：
SONG, L;TROGLER, WC
在反式-[Os(CO3(PPh3)2)]与Ag（O2CCF3）氧化过程中，锇银键配合物的形成先于Os—> Ag的实际电子转移，如电化学测量结果和标题配合物的x射线结构分析所示（未显示膦配体的苯基）。因此，该配合物可以被认为是有机金属化合物被Ag+氧化的中间体的模型。
The formation of a complex with an osmium-silver bond precedes the actual electron transfer Os --> Ag in the oxidation of trans-[Os(CO3(PPh3)2)] with Ag(O2CCF3) as indicated by the results of electrochemical measurements and the X-ray structure analysis of the title complex depicted below (the phenyl groups of the phosphine ligands are not shown). This complex can thus be considered a model for intermediates in the oxidation of organometallic compounds by Ag+.