Juggling Optoelectronics and Catalysis: The Dual Talents of Bench Stable 1,4-Azaborinines.
Juggling Optoelectronics and Catalysis: The Dual Talents of Bench Stable 1,4-Azaborinines.
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兼顾光电和催化：稳定 1,4-氮杂硼烷的双重才能。
DOI：
10.1002/chem.202301944
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发表时间：
2023
期刊：
影响因子：
--
通讯作者：
Van Beek CM
中科院分区：
文献类型：
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作者：
Van Beek CM
硼和氮掺杂的多环芳烃（B‐ PAH）已经在有机电子领域站稳脚跟。然而，它们的催化潜力在很大程度上尚未开发。在这项研究中，我们合成并合成了两个工作台稳定的B，N-掺杂的PAH衍生物的基础上的1，4-氮杂硼杂环丁烷基序。最重要的是，蒽衍生的结构是还原各种羰基和亚胺的有效催化剂。这些结果强调了B，N-PAH在催化转化中的潜力，为在这一化学空间进行更深入的探索奠定了基础。
Boron‐ and nitrogen‐doped polycyclic aromatic hydrocarbons (B‐PAHs) have established a strong foothold in the realm of organic electronics. However, their catalytic potential remains largely untapped. In this study, we synthesise and characterise two bench stable B,N‐doped PAH derivatives based on a 1,4‐azaborinine motif. Most importantly, the anthracene derived structure is an efficient catalyst in the reduction of various carbonyls and imines. These results underscore the potential of B,N‐PAHs in catalytic transformations, setting the stage for deeper exploration in this chemical space.