A Copper(I)‐Complexed Rotaxane with Two Fullerene Stoppers: Synthesis, Electrochemistry, and Photoinduced Processes
A Copper(I)‐Complexed Rotaxane with Two Fullerene Stoppers: Synthesis, Electrochemistry, and Photoinduced Processes
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DOI：
10.1002/(sici)1521-3765(19980310)4:3
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发表时间：
1998-03
期刊：
影响因子：
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通讯作者：
N. Armaroli;F. Diederich;C. Dietrich-Buchecker;L. Flamigni;G. Marconi;J. Nierengarten;J. Sauvage
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文献类型：
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作者：
N. Armaroli;F. Diederich;C. Dietrich-Buchecker;L. Flamigni;G. Marconi;J. Nierengarten;J. Sauvage
由配位环、铜（I）中心和穿入环内的双官能化片段组成的超分子阵列用C60衍生物处理，得到具有两个富勒烯作为终止物的轮烷（右）。轮烷相对于单个组件，methanofullerene和CuI络合物的物理性质的变化，被分配到发生组件间的能量和电子转移过程。
A supermolecular array consisting of a coordinating ring, a copper(I) centre and a difunctionalized fragment threaded inside the ring is treated with a C60 derivative to afford a rotaxane with two fullerenes as stoppers (right). The changes in the photophysical properties of the rotaxane with respect to the individual components, a methanofullerene and a CuI complex, were assigned to the occurrence of intercomponent energy- and electron-transfer processes.