Three-dimensional ferromagnetic frameworks of syn-anti-type carboxylate-bridged NiII and CoII coordination polymers
Three-dimensional ferromagnetic frameworks of syn-anti-type carboxylate-bridged NiII and CoII coordination polymers
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DOI：
10.1246/cl.2007.1184
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发表时间：
2007-08
影响因子：
1.6
通讯作者：
Ko Yoneda;M. Ohba;Takuya Shiga;H. Oshio;S. Kitagawa
中科院分区：
文献类型：
--
作者：
Ko Yoneda;M. Ohba;Takuya Shiga;H. Oshio;S. Kitagawa
合成了两种新型配位聚合物[M（L）（MeOH）2 ] n（MII = Ni，Co; H2 L = E，E-粘康酸），它们具有由顺反型羧酸桥延伸的二维网格层构成的三维柱撑层结构，其中Ni II化合物在1.7K下表现出铁磁有序性.
Two novel coordination polymers, [M(L)(MeOH) 2 ] n (M II = Ni, Co; H 2 L = E,E-muconic acid) having 3-D pillared-layer structure based on 2-D grid sheet extended by syn-anti-type carboxylate-bridges were prepared and Ni II compound showed a ferromagnetic ordering at 1.7 K.