RAMAN SPECTRA OF POLYBUTADIENE RUBBERS

RAMAN SPECTRA OF POLYBUTADIENE RUBBERS
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DOI:
10.1021/ma60011a018
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发表时间:
1969-01-01
期刊:
影响因子:
5.5
通讯作者:
KOENIG, JL
KOENIG, JL
中科院分区:
化学1区
文献类型:
--
作者:
CORNELL, SW;KOENIG, JL

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给出了c/j-1,4-,反式A-和1,2-聚丁二烯的拉曼光谱。对这些模型化合物的光谱分析和法坐标结果,使拉曼光谱可以根据构型结构类型进行分类。拉曼碳-碳双键伸缩振动可以唯一地描述聚丁二烯的结构含量。
The Raman spectra of c/j-1, 4-, transA A-, and 1, 2-polybutadiene are presented. Analysis of the spectra of these model compounds, and the normal coordinate results, enable the Raman frequencies to be classified by configurational structure type. TheRaman carbon-carbon double bond stretching vibrations can beused to describe uniquely the structure content in polybutadienes.