Preparation of amine-containing poly(amide-sullfone)s using vinylsulfone reactive monomers and their properties
Preparation of amine-containing poly(amide-sullfone)s using vinylsulfone reactive monomers and their properties
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DOI：
10.1007/bf03218747
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发表时间：
2007-02-01
影响因子：
2.4
通讯作者：
Gong, Myoung-Seon
中科院分区：
文献类型：
--
作者：
Jeon, Young-Min;Lim, Tai-Ho;Gong, Myoung-Seon
以对氨基苯基乙烯基砜(1)与己二酰氯、对苯二甲酰氯、间苯二甲酰氯等各种酰氯反应制备了一系列新型含乙烯基砜单体。最后，使用N,N-二甲基乙二胺(DMEDA)、对苯二胺和哌嗪通过迈克尔型加成聚合制备含叔胺的聚(酰胺-砜)。为了评估选择性渗透膜和酶底物的相关性质，检查了各种物理性质，例如分子量、溶解度、季铵化行为和热性质。
A series of new, vinyl sulfone-containing monomers was prepared by p-aminophenyl vinyl sulfone (1) with various acid chlorides such as adipoly chloride, terephthaloyl chloride and isophthaloyl chloride. Finally, tertiary amine-containing poly(amide-sulfone)s were prepared by the Michael-type addition polymerization using N,N-dimethylethylenediamine (DMEDA), p-phenylenediamine and piperazin. To evaluate the relevant properties for permselective membranes and enzyme substrate, various physical properties such as molecular weight, solubility, quaternization behavior and thermal properties were examined.