Chemistry and structure by design: ordered CuNi(CN)4 sheets with copper(ii) in a square-planar environment.
Chemistry and structure by design: ordered CuNi(CN)4 sheets with copper(ii) in a square-planar environment.
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DOI：
10.1039/c5dt01127b
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发表时间：
2015-07
影响因子：
4
通讯作者：
A. Chippindale;S. Hibble;E. Marelli;E. Bilbé;A. Hannon;M. Zbiri
中科院分区：
文献类型：
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作者：
A. Chippindale;S. Hibble;E. Marelli;E. Bilbé;A. Hannon;M. Zbiri
层状铜镍氰化物，CuNi（CN）4，是一种二维负热膨胀材料，是一系列由Ni（CN）2衍生的含铜氰化物之一。在CuNi（CN）4中，与Ni（CN）2不同，氰化物基团是有序的，生成正方形平面Ni（CN）4和Cu（NC）4单元。通过正方形平面几何Cu（II）在一个扩展的固体是非常不寻常的。
Layered copper-nickel cyanide, CuNi(CN)4, a 2-D negative thermal expansion material, is one of a series of copper(ii)-containing cyanides derived from Ni(CN)2. In CuNi(CN)4, unlike in Ni(CN)2, the cyanide groups are ordered generating square-planar Ni(CN)4 and Cu(NC)4 units. The adoption of square-planar geometry by Cu(ii) in an extended solid is very unusual.