New framework iodoargentates: M(en)3Ag2I4 (M=Zn, Ni) with tridymite topology.
New framework iodoargentates: M(en)3Ag2I4 (M=Zn, Ni) with tridymite topology.
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DOI：
10.1021/ic7025158
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发表时间：
2008-04
影响因子：
4.6
通讯作者：
Yan‐Si Jiang;Hua-gang Yao;S. Ji;Min Ji;Y. An
中科院分区：
文献类型：
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作者：
Yan‐Si Jiang;Hua-gang Yao;S. Ji;Min Ji;Y. An
通过自组装反应合成了两种新型骨架化合物：Zn(en) 3Ag2I4 (1) 和 Ni(en) 3Ag2I4 (2)。它们都包含一个意想不到的框架，具有鳞石英拓扑结构的Ag2I4(2-)，并且离散的M(en)3(2+)阳离子位于通道中。研究了它们的热性质和圆二色光谱。
Two novel framework compounds, Zn(en) 3Ag2I4 (1) and Ni(en) 3Ag2I4 (2), have been synthesized by a self-assembly reaction. Both of them contain an unexpected framework, Ag2I4(2-) with tridymite topology, and the discrete M(en)3(2+) cations are located in the channels. Their thermal properties and circular dichroism spectra were investigated.