Dichlorido(2,9-dimethyl-1,10-phenanthroline-κN,N')copper(II).

Dichlorido(2,9-dimethyl-1,10-phenanthroline-κN,N')copper(II).
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二氯(2,9-二甲基-1,10-菲咯啉-γN,N)铜(II)。

DOI:
10.1107/s1600536809034187
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发表时间:
2009
期刊:
Acta crystallographica. Section E, Structure reports online
影响因子:
--
通讯作者:
Zhong,H
Zhong,H
中科院分区:
--
文献类型:
--
作者:
Wang,BS;Zhong,H

文献摘要

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In the title compound, [CuCl2(C14H12N2)], the complex molecule has m symmetry, with the mirror plane oriented parallel to the planar molecule and the ligated CuII atom. The metal centre has a distorted tetrahedral coordination formed by two N atoms from one 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. There is intermolecular π–π stacking between adjacent 2,9-dimethyl-1,10-phenanthroline ligands, with a centroid–centroid distance of 3.733 (2)Å.